The first example of a reversibly reducible Co-II complex with an anionic 2-thiohydantoin-type ligandстатья
Информация о цитировании статьи получена из
Web of Science
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 29 мая 2015 г.
Аннотация:The reaction of the potassium salt of 3-phenyl-5(Z)-(pyridin-2-ylmethylene)-2-thioxoimidazolidin-4-one (KL) with CoCl(2)center dot 6H(2)O in MeCN results in formation of the neutral complex (CoL2)-L-II. According to single-crystal X-ray analysis, the Coll centre is coordinated to four nitrogen atoms of two organic ligands and has a distorted tetrahedral geometry. This complex undergoes electrochemical reduction with consequent two reversible and one quasi-reversible stages.