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Structure and ion-complexing properties of an aza-15-crown-5 ether dye: synthesis, crystallography, NMR spectroscopy, spectrophotometry and potentiometryстатья
Информация о цитировании статьи получена из
Scopus,
Web of Science
Дата последнего поиска статьи во внешних источниках: 30 октября 2013 г.
- Авторы: Alfimov M.V., Churakov A.V., Fedorov Y.V., Fedorova O.A., Gromov S.P., Hester R.E., Howard J.A.K, Kuzmina L.G., Lednev I.K., Moore J.N.
- Журнал: Journal of the Chemical Society. Perkin Transactions 2
- Номер: 11
- Год издания: 1997
- Первая страница: 2249
- Последняя страница: 2256
- DOI: 10.1039/a703347h
- Аннотация: The perchlorate of 2-[2-[4-(13-aza-1,4,7,10-tetroxa-13-cyclopentadecyl)phenyl] ethenyl}-3-ethyl- benzothiazolium (3) has been synthesised and its structure determined in the crystalline state by X-ray diffraction and in solution in acetonitrile by H-1 NMR methods, Complexation with barium and silver cations in solution has been studied in comparison with other model azacrown molecules by spectrophotometric and potentiometric methods. With the exception of the puckered azacrown moiety, the structure of 3 is remarkably planar, consistent with extensive pi-conjugation throughout the remainder of the molecule in both solid and solution states. Compound 3 forms a stable 1:1 complex with Ba2+ ions in acetonitrile, with a stability constant of K-1 = 80 +/- 10 dm(3) mol(-1); the complexation results in major changes in the electronic absorption spectrum of 3, consistent with binding to the azacrown moiety, A model compound, phenylaza-15-crown-5 (2a), was found to bind Ba2+ to form both a I: 1 ligand-metal complex (LM), with a stability constant of K-1 = (2.0 +/- 0.2) x 10(4) dm(3) mol(-1), and a 2:1 (L2M) complex, with a stability constant of K-2 = 220 +/- 20 dm(3) mol(-1) for binding of the second Ligand. The electronic absorption and NMR spectra both indicate binding of the 'hard' Ba2+ cation to the azacrown oxygen atoms, However, by contrast, the evidence from NMR data shows that the 'soft' Ag+ cation complexes with 2a mainly through a strong interaction with the azacrown nitrogen atom, giving a 1 :1 complex with a stability constant of K-1 = 6 +/- 1 dm(3) mol(-1), determined by potentiometry. No complexation of 3 with Ag+ is observed, Studies of the simple aza-15-crown-5 ether reveal strong complexation with both Ba2+(K-1 x K-2 > 10(12)dm(6) mol(-2)) and Ag+ [K-1 = (1.15 +/- 0.10) x 10(4) dm(3) mol(-1) and K-2= 450 +/- 20 dm(3) mol(-1)].
- Добавил в систему: Громов Сергей Пантелеймонович