Influence of the nature of the supporting electrolyte on the adsorption of substances forming two-dimensional condensed layers at the mercury electrolyte interfaceстатья
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Дата последнего поиска статьи во внешних источниках: 12 октября 2013 г.
Аннотация:The influence of the nature and concentration of the supporting electrolyte on the adsorption of substances which form two-dimensional condensed layers has been investigated by recording C-E and C-t curves. The choice of spatial isomers of adamantanol and borneol as objects of investigation makes it possible to attribute all the differences in the kinetics of the formation of the condensed layers of these iosmers to the different conditions for the occurrence of the respective adsorption steps. It is shown that the specifically adsorbed background ions and the concentration of the supporting electrolyte have a strong influence on the range of potentials for the adsorption of the surfactants and the kinetics of the filling of the surface.