Metal solvent interaction and ion adsorption influence of solvent and metal natureстатья
Информация о цитировании статьи получена из
Web of Science
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 29 мая 2015 г.
Авторы:
Levi M.D. ,
Shlepakov A.V. ,
Damaskin B.B. ,
Bagotskaya I.A.
Журнал:
Journal of Electroanalytical Chemistry
Том:
138
Номер:
1
Год издания:
1982
Издательство:
Elsevier Sequoia
Местоположение издательства:
Switzerland
Первая страница:
1
Последняя страница:
27
DOI:
10.1016/0022-0728(82)87124-6
Аннотация:
The influence of the lyophilic properties of an electrode on the specific adsorption of ions is analyzed by comparing the electric double-layer structure at mercury, bismuth and eutectic (In + Ga) alloy in acetonitrile and dimethylsulfoxide in inactive electrolyte solutions and in solutions containing surface-active ions. A method is proposed for estimating the free energy of interaction of solvent molecules with the electrode surface from adsorption isotherm parameters. It is shown, as exemplified by dimethylsulfoxide, that the lyophilic series of metals established from differential capacity values in inactive electrolyte solutions correlates with the change in the values of the free energy of interaction of dimethylsulfoxide molecules with the electrode, estimated by the method proposed in this paper. The influence of the nature of the electrode and the salvation energy of ions in different solvents on the surface activity series of these ions is examined. © 1982.
Добавил в систему:
Дамаскин Борис Борисович