Chemical polymerization of aniline in the presence of mixtures of polymeric sulfonic acidsстатья
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Дата последнего поиска статьи во внешних источниках: 20 декабря 2017 г.
Аннотация:The template polymerization of aniline in the presence of polymeric sulfonic acids of various structures and their mixtures is studied. In the latter case, the dominant effect of a polyacid on the kinetics of aniline
polymerization and the electronic structure of the resulting polyaniline complex is observed. As shown by viscometry measurements and IR studies, the intermolecular interaction between polyacids in their mixtures that leads
to a change in the conformation of a flexible chain polyacid is responsible for the dominant effect of a rigid chain
polyacid. The spectral and electrical properties of polyaniline based interpolymer complexes are examined.