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Origin of voltage decay in high-capacity layered oxide electrodesстатья
Статья опубликована в высокорейтинговом журнале
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 11 мая 2015 г.
- Авторы: Sathiya M., Abakumov A.M., Foix D., Rousse G., Ramesha K., Saubanère M., Doublet M.L., Vezin H., Laisa C.P., Prakash A.S., Gonbeau D., Van Tendeloo G., J-M Tarascon
- Журнал: Nature Materials
- Том: 14
- Год издания: 2015
- Издательство: Nature Publishing Group
- Местоположение издательства: United Kingdom
- Первая страница: 230
- Последняя страница: 238
- DOI: 10.1038/nmat4137
- Аннотация: Although Li-rich layered oxides (Li1+xNiyCozMn1−x−y−zO2 > 250 mAh g−1) are attractive electrode materials providing energy densities more than 15% higher than today’s commercial Li-ion cells, they suffer from voltage decay on cycling. To elucidate the origin of this phenomenon, we employ chemical substitution in structurally related Li2RuO3 compounds. Li-rich layered Li2Ru1−yTiyO3 phases with capacities of ~240 mAh g−1 exhibit the characteristic voltage decay on cycling. A combination of transmission electron microscopy and X-ray photoelectron spectroscopy studies reveals that the migration of cations between metal layers and Li layers is an intrinsic feature of the charge–discharge process that increases the trapping of metal ions in interstitial tetrahedral sites. A correlation between these trapped ions and the voltage decay is established by expanding the study to both Li2Ru1−ySnyO3 and Li2RuO3; the slowest decay occurs for the cations with the largest ionic radii. This effect is robust, and the finding provides insights into new chemistry to be explored for developing high-capacity layered electrodes that evade voltage decay.
- Добавил в систему: Абакумов Артем Михайлович