Synthesis and Application of N-Cyclopalladated Ferrocene Derivativesстатья
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Дата последнего поиска статьи во внешних источниках: 12 сентября 2019 г.
Аннотация:Progress in the synthesis and application of the cyclopalladated derivatives of ferrocene with a donor nitrogen atom in the directing group is surveyed including the planar chirality and enantioselective catalysis of organic reactions and rearrangements. Transannular palladation has been found giving achiral 1,1'-disubstituted ferrocenes of ansa-structure. Cyclopalladated ferrocenes have been widely used as catalysts in the cross-coupling reactions (Suzuki, Heck, aza-Claisen, etc. )