Lattice dynamics of quasi-two-dimensional CdSe nanoplatelets and their Raman and infrared spectraстатья Исследовательская статья

Статья опубликована в высокорейтинговом журнале

Информация о цитировании статьи получена из Scopus, Web of Science
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 26 января 2018 г.

Работа с статьей


[1] Lebedev A. I. Lattice dynamics of quasi-two-dimensional cdse nanoplatelets and their raman and infrared spectra // Physical Review B. — 2017. — Vol. 96, no. 18. — P. 184306–1–184306–8. Phonon spectra of CdSe nanoplatelets (2–6 ML) with the zinc-blende structure were calculated from first principles within the density-functional theory. It turned out that the Lamb modes in nanoplatelets are in fact optical rather than acoustic vibrations. Phonon spectra of the nanoplatelets show the appearance of a large number of low-frequency modes inherited from TA phonons in bulk CdSe. Calculations of the Raman spectra indicate a need to revise the interpretation of available experimental data. The largest contribution to the Raman spectra is provided by the quasi-Lamb modes with the A1 symmetry. The B2 modes whose frequencies depend on the environment of nanoplatelets and whose properties are closest to the properties of LO phonons explain the results obtained in the “nanoparticle-on-mirror” geometry. The features in Raman spectra previously attributed to surface optical (SO) modes should be interpreted as a manifestation of lower-order quasi-Lamb A1 modes. Calculations of the infrared spectra find, in addition to the TO phonon line, the appearance of intense lines from surface modes originating from terminating F(Cl) atoms on the surface of nanoplatelets and true SO modes. [ DOI ]

Публикация в формате сохранить в файл сохранить в файл сохранить в файл сохранить в файл сохранить в файл сохранить в файл скрыть