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2,2 '-Dipyridyl-6,6 '-dicarboxylic acid diamides: Synthesis, complexation and extraction propertiesстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
- Авторы: Alyapyshev M., Babain V., Borisova N., Eliseev I., Kirsanov D., Kostin A., Legin A., Reshetova M., Smirnova Z.
- Журнал: Polyhedron
- Том: 29
- Номер: 8
- Год издания: 2010
- Издательство: Pergamon Press
- Местоположение издательства: United States
- Первая страница: 1998
- Последняя страница: 2005
- DOI: 10.1016/j.poly.2010.03.021
- Аннотация: New ligands for complexing of the post-transition metals - diamides of 2,2'-bipyridyl-6,6'-dicarboxylic acid were developed, synthesised and characterised. They were proposed to be effective extractants towards americium. The structures of the amides were studied in solid as well as in solution. The extraction of Am and lanthanides depending on diamide structure, chlorinated cobalt dicarbollide (CCD) - diamide ratio, type of diluent was studied. The optimal conditions for Am/REE separation were determined. The properties of new potentiometric sensors on the base of 2,2'-dipyridyl-6,6'-dicarboxylic acid diamides were studied. The correlation structure vs. properties of ionophores (i.e. extractants), their sensitivity and selectivity in sensor analysis and extraction are discussed. (c) 2010 Elsevier Ltd. All rights reserved.
- Добавил в систему: Борисова Наталия Евгеньевна