|
ИСТИНА |
Войти в систему Регистрация |
Интеллектуальная Система Тематического Исследования НАукометрических данных |
||
On the Formation of Hollow Metal-Oxide Particles in the Oxidation of Compacted Iron Powderстатья Исследовательская статья
- Автор: Kotenev V.A.
- Журнал: Protection of Metals and Physical Chemistry of Surfaces
- Том: 61
- Номер: 6
- Год издания: 2025
- Издательство: Pleiades Publishing, Ltd
- Местоположение издательства: Road Town, United Kingdom
- Первая страница: 1267
- Последняя страница: 1275
- DOI: 10.1134/S2070205125701163
- Аннотация: Thermogravimetry, differential scanning calorimetry, and scanning electron microscopy were used to study the change in the structure of particles of metal-oxide composites obtained by compacting iron powder and subsequent annealing with an increase in temperature from 20 to 800°C in air and in an argon atmosphere. It is shown that, after high-temperature annealing, vacancy pores and cavities are formed in the volume of metal-oxide particles of the composite, which are associated with the external diffusion of metal ions through the oxide layer and counterdiffusion and injection of vacancies into the metal with their subsequent condensation into pores in the internal volume of metal-oxide particles (the Kirkendall effect). The reason for the acceleration of diffusion of metal cations and vacancies is associated with the presence of a difference in internal stresses in the growing oxide layer on the surface of the metal particles of the composite. It has been shown that differences in the diffusion coefficients of cations and anions through the oxide layer (the Kirkendall effect) can be used to synthesize hollow iron-oxide particles and composite materials based on them, which can be used for encapsulation and as adsorbents, as well as to create new types of hybrid materials for catalytic or biological applications.
- Добавил в систему: Котенев Владимир Анатольевич