Co-ligand tuning of MOF structural anisotropy for giant optical birefringenceстатья
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Дата последнего поиска статьи во внешних источниках: 23 января 2026 г.
Аннотация:The control of the structural anisotropy of metal–organic frameworks (MOFs) by tuning their co-ligand composition to enhance the birefringence properties is demonstrated. A set of Cd-based MOFs with three co-ligands and H4TCPB were synthesised. We experimentally revealed the evolution of the MOF structural anisotropy and birefringence, which was equal to maximal Δn = 0.223 in experiments and Δn = 0.58 in theory within the visible spectral range.