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Интеллектуальная Система Тематического Исследования НАукометрических данных |
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Fe DOPED NONSTOICHIOMETRICAL ZnSтезисы доклада
- Авторы: Potapova Ksenia A., Kim Karina G., Zykova Marina P., Voronina Elena A., Mozhevitina Elena N., Avetisov Roman I., Avetissov Igor C., Tran Cong K.
- Сборник: ABSTRACTS & PROGRAM THE 1ST INTERNATIONAL CONFERENCE ON ADVANCED AND MULTIFUNCTIONAL MATERIALS (ICAMM’24)
- Тезисы
- Год издания: 2024
- Место издания: Ho Chi Minh City, Vietnam Ho Chi Minh City, Vietnam
- Первая страница: 90
- Последняя страница: 90
- Аннотация: Fe-doped ZnS (Fe:ZnS) crystals and ceramics are used as active IR laser media. To achieve the advanced laser properties, the reliable data on the Fe concentration and material synthesis conditions is essential. In this study, we invetstigated the Fe solubility in nonstoichiometric ZnS crystals under bivariant equilibrium conditions of SZnS-SFeS-V. Sixty seven isothermal TX- Y cross-sections of Zn-S-Fe ternary system were analyzed by the graphical thermodynamics technique and were proved by X-ray analysis using the «frozen equilibrium» technique. The ternary system was analyzed, from the entire melting to the complete solidification. The synthesis conditions of Fe:ZnS preparation were determined based on the corresponding cross-sections in a temperature range of 1173 to1323 K. The nonstoichiometry of ZnS crystal was determined by the «extraction» method [1]. The Fe concentration was measured by the ICP-MS analysis. The results showed that the Fe solubility in nonstoichiometric ZnS reaches its maximum value at 1273 K, attaining a concentration of 610-3 wt. % at nearly stoichiometric composition (510-10 mole excess Zn/mole ZnS). The effects of nonstoichiometry and the Fe concentration on the mid-IR properties of Fe: ZnS were also established. According to the obtained IR luminescent properties the synthesized ZnS.Fe is perspective for laser application.
- Добавил в систему: Аветисов Игорь Христофорович