Heterometallic NIR-emitting nanothermometers by click-reaction between two lanthanide complexes

Авторы: Koshelev Daniil S., Medved'ko Alexey, Goloveshkin Alexander S., Nelubina Yulia V., Maloshitskaya Olga A., Safiullina Elnara S., Gracheva Yulia Alexandrovna, Nikitin Evgeny A., Lepnev Leonid, Vatsadze Sergey, Utochnikova Valentina V.
Журнал: Journal of Materials Chemistry С
Год издания: 2024
Издательство: Royal Society of Chemistry
Местоположение издательства: United Kingdom
DOI: 10.1039/d4tc03970j
Аннотация: Heterobimetallic lanthanide conjugates were obtained by click reaction between two monometallic lanthanide complexes with Schiff bases for the first time. For that, novel azido- and ethynyl-substituted ligands, as well as their lanthanide complexes, were obtained and characterised; two new crystal structures were obtained. Click-reaction between ligands and complexes was performed, and the latter was demonstrated to result in the conjugates {Ln1-Ln2} formation. Among the obtained conjugates, {Yb-Nd} and {Yb-Er} demonstrated intense NIR emission with temperature sensitivity in the physiological range of up to 3%/K.
Добавил в систему: Кошелев Даниил Сергеевич

№	Имя	Описание	Имя файла	Размер	Добавлен
1.	250213154112_0004.pdf		250213154112_0004.pdf	101,3 КБ	13 февраля 2025 [asg_xrlab]
2.	Полный текст	Авторский экземпляр	authorreprints.pdf	1,4 МБ	24 декабря 2024 [Lamblador]

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