Место издания:“Admiral Print” LLC Moscow Federal Territory “Sirius”, Russia
Первая страница:79
Аннотация:Our research group is actively developing catalysts for the production of biodegradable polymers1-2, as well asfunctionalized polymers3 for gas separation membranes used in fields, related with increasing environmental protectionrequirements.As one of the key base material for gas separation, liquid-crystal polymer membranes can exhibit high permeabilitywith high thermally controlled selectivity.This work proposes methods for the synthesis of monomers to create materials based on functionalized norbornenederivatives.The synthesized exo-substituted norbornenes, the structure of which was confirmed by 1H and 13C NMR spectroscopy,showed high activity in metathesis polymerization, and the resulting polymer materials contain a liquid-crystallinephase.References1. Zaitsev K.V., Trubachev A.D., Oprunenko Y.F., Piskun Y.A., Vasilenko I.V., Churakov A.V., Kostjuk S.V. Molecules, 2023, 28, 1262.2. Fedulin A.I., Churakov A.V., Zaitsev K.V. Mendeleev Commun., 2021, 31(6), 847.3. Guseva M.A., Lezhnin P.P., Alentiev D.A., Zaitsev K.V., Bermeshev M.V. Polym. Sci., 2023, 65, 196.