|
ИСТИНА |
Войти в систему Регистрация |
Интеллектуальная Система Тематического Исследования НАукометрических данных |
||
Synthesis, Structure, and Properties of 1,3‐Diaryl‐7‐imino‐1,7‐dihydrobenzo[e][1,2,4]triazines: Products of Unexpected Conversion of Polyfluorinated Blatter Radicalsстатья
- Авторы: Gulyaev Dmitry, Serykh Andrey, Gadimov Nurlan, Shangin Pavel, Syroeshkin Mikhail, Sosunov Egor, Tretyakov Evgeny
- Журнал: European Journal of Organic Chemistry
- Год издания: 2024
- Издательство: John Wiley & Sons Ltd.
- Местоположение издательства: United Kingdom
- DOI: 10.1002/ejoc.202400494
- Аннотация: Derivatives of the first substituted 7-imino-1,7-dihydrobenzo[e][1,2,4]triazines, namely 1-(2,3,5,6-tetrafluoropyridin-4-yl)-N,3-diphenyl-7-(phenylimino)-1,7-dihydrobenzo[e][1,2,4]triazin-6-amine and 1-(pentafluorophenyl)-N-phenyl-7-(phenylimino)-3-(2,3,4,5-tetrafluorophenyl)-1,7-dihydrobenzo[e][1,2,4]triazin-6-amine, were unexpectedly isolated as the only products in yields of about 20-30% after an attempt to obtain Blatter radicals from the corresponding amidrazones bearing polyfluorinated electron-withdrawing substituents. All new compounds were fully characterized, and their molecular and crystal structure was determined by single-crystal X-ray diffraction.
- Добавил в систему: Гуляев Дмитрий Александрович