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Sulfur in Waste-Free Sustainable Synthesis: Advancing Carbon–Carbon Coupling Techniquesстатья
Статья опубликована в высокорейтинговом журнале
Информация о цитировании статьи получена из
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 15 мая 2024 г.
- Авторы: Shlapakov Nikita S., Kobelev Andrey D., Burykina Julia V., Cheng Yuan-Zheng, You Shu-Li, Ananikov Valentine P.
- Журнал: Angewandte Chemie - International Edition
- Том: 63
- Номер: 18
- Год издания: 2024
- Издательство: John Wiley & Sons Ltd.
- Местоположение издательства: United Kingdom
- Первая страница: e202402109
- DOI: 10.1002/anie.202402109
- Аннотация: Abstract This review explores the pivotal role of sulfur in advancing sustainable carbon-carbon (C−C) coupling reactions. The unique electronic properties of sulfur, as a soft Lewis base with significant mesomeric effect make it an excellent candidate for initiating radical transformations, directing C−H-activation, and facilitating cycloaddition and C−S bond dissociation reactions. These attributes are crucial for developing waste-free methodologies in green chemistry. Our mini-review is focused on existing sulfur-directed C−C coupling techniques, emphasizing their sustainability and comparing state-of-the-art methods with traditional approaches. The review highlights the importance of this research in addressing current challenges in organic synthesis and catalysis. The innovative use of sulfur in photocatalytic, electrochemical and metal-catalyzed processes not only exemplifies significant advancements in the field but also opens new avenues for environmentally friendly chemical processes. By focusing on atom economy and waste minimization, the analysis provides broad appeal and potential for future developments in sustainable organic chemistry.
- Добавил в систему: Кобелев Андрей Дмитриевич