Novel host molecules based on calix[4]arenesтезисы доклада

Дата последнего поиска статьи во внешних источниках: 23 ноября 2017 г.

Работа с тезисами доклада


[1] Novel host molecules based on calix[4]arenes / I. Vatsouro, A. Gorbunov, K. Puchnin, V. Kovalev // Book of abstracts 8th International IUPAC Symposium Macro- and Supramolecular Architectures and Materials: Multifunctional Materials and Structures (MAM-17). — ISBN 978-5-7396-0369-2. — Publishing House of I.M. Sechenov First MSMU Москва, 2017. — P. 12. Calixarenes is well known family of host molecules with wide range of applications in supramolecular chemistry. Our research group has focused over the last decade on the design, synthesis and host-guest properties of the different types of these macrocyclic compounds. In this lecture we will discuss synthetic approaches, ionophore and catalytic properties of novel host molecules based on calix[4]arenes[1-4], including: • triazole-containing calix[4]arenes 1; • p-sulfonatocalix[4]arenes with extended functionality at narrow rim 2; • calix[4]arenes with β-diketones units at narrow rim 3; • calix[4]arene tubes bearing anchoring groups 4. References 1. Puchnin K., Zaikin P., Cheshkov D., Vatsouro I., Kovalev V. Calix[4]tubes: An Approach to Functionalization. // Chem. Eur. J. 2012, 18(35), 10954–10968. 2. Puchnin K., Cheskov D., Zaikin P., Vatsouro I., Kovalev V. Tuning conformations of calix[4]tubes by weak intramolecular interactions. // New J. Chem. 2013, 37(2), 416-424. 3. Gorbunov A., Cheskov D., Kovalev V., Vatsouro I. Copper(I)-Catalyzed Cycloaddition of Azides to Multiple Alkynes: A Selectivity Study Using a Calixarene Framework. // Chem. Eur. J. 2015, 21(26), 9528–9534. 4. Gorbunov A., Sokolova N., Kudryashova E. V., Nenajdenko V., Kovalev V., Vatsouro I. Chiral heteroditopic baskets designed from triazolated calixarenes and short peptides. // Chem. Eur. J. 2016, 22(35), 12415–12423.

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