Conversion of C-2-C-4 alcohols over copper-containing catalysts on carbon and fluorocarbon fibersстатья

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Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.

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[1] Conversion of c-2-c-4 alcohols over copper-containing catalysts on carbon and fluorocarbon fibers / E. A. Tveritinova, Y. N. Zhitnev, T. M. Roshchina, V. V. Lunin // Russian Journal of Physical Chemistry A. — 2011. — Vol. 85, no. 7. — P. 1124–1129. Carbon and fluorocarbon fibers were used as carriers for the preparation of copper catalysts from copper oxalate as precursor. The catalytic properties of catalyst were studied in the reaction of the dehydrogenation of C-2-C-4 alcohols by the pulsed microcatalytic method. The effect of the copper content in the catalyst, the reaction temperature on the degree of conversion, and the relation of the reaction channels were studied. The electron microphotographs were obtained, specific surfaces were measured, and X-ray pictures and infrared spectra of catalysts were taken. The activity of the catalysts on the carbon and fluorocarbon fibers in the dehydration-dehydrogenation reactions of C-2-C-4 alcohols was comparatively estimated. It was shown that the selectivity of the products from the dehydrogenation reaction is higher for the Cu-fluorocarbon fiber catalyst. [ DOI ]

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