|
ИСТИНА |
Войти в систему Регистрация |
Интеллектуальная Система Тематического Исследования НАукометрических данных |
||
Dual Effect of Organomercury Compounds on Peroxide Oxidation of Oleic Acidстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 12 марта 2014 г.
- Авторы: Milaeva E.R., Kirillova L.N., Berberova N.T., Pimenov Yu T., Tyurin V.Yu, Grigor’ev E.V., Gracheva Yu A., Petrosyan and V.S
- Журнал: Russian Journal of General Chemistry
- Том: 72
- Номер: 5
- Год издания: 2002
- Издательство: Maik Nauka/Interperiodica Publishing
- Местоположение издательства: Russian Federation
- Первая страница: 710
- Последняя страница: 714
- DOI: 10.1023/A:1019547900028
- Аннотация: Oxidation of oleic acid with atmospheric oxygen in the presence of HgCl2 and various organo- mercury compounds (methylmercury iodide, isopropylmercury bromide, n-hexylmercury bromide, phenylmercury bromide, diphenylmercury, p-tolylmercury bromide, bis-p-tolylmercury) was studied. Mercury compounds exert a dual effect on accumulation of oleic acid hydroperoxide in the temperature range 20-90°C. Below 50°C, the concentration of the hydroperoxides formed in the presence of mercury compounds is lower, and at higher temperatures, higher than in the experiments performed without mercury compounds. Comparison of the concentrations of oleic acid hydroperoxides with those of their transformation products, carbonyl compounds, determined spectrophotometrically, shows that actually organomercury compounds and HgCl2 accelerate peroxide oxidation at all the studied temperatures. Decreased accumulation of peroxides below 50°C is apparently due to the fact that the rate of their reaction with organomercury compounds is higher than the rate of their formation.
- Добавил в систему: Тюрин Владимир Юрьевич
Прикрепленные файлы
| № | Имя | Описание | Имя файла | Размер | Добавлен |
|---|---|---|---|---|---|
| 1. | art3A10.10232FA3A1019547900028.pdf | art3A10.10232FA3A1019547900028.pdf | 48,6 КБ | 14 ноября 2014 [V.Tyurin] |