Electrophoretic study of cationic cobalt(III) complexes with [N2O] and [N2O2] Schiff base ligandsстатья
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Авторы:
Nesterenko P. ,
Levitin I. ,
Chernoglazova N. ,
Paskonova E. ,
Penner N. ,
Tsikalova M.
Журнал:
Inorganica Chimica Acta
Том:
280
Номер:
1-2
Год издания:
1998
Издательство:
Elsevier BV
Местоположение издательства:
Netherlands
Первая страница:
295
Последняя страница:
301
Аннотация:
The electrophoretic migration behavior of acid-sensitive cationic alkylcobalt(III) complexes with tridentate Schiff bases and amines as well as that of related ’inorganic’ cobalt(III) chelates with tridentate and tetradentate Schiff bases was studied. A correlation of the electrophoretic mobility of the organocobalt complexes in question with their structure was established. An attempt to optimize the analytical procedures for capillary electrophoretic separation of these rather labile complex cations is outlined. Their decomposition in solutions under ambient conditions was surveyed using this technique. © 1998 Elsevier Science S.A. All rights reserved.
Добавил в систему:
Нестеренко Павел Николаевич