Destruction of globules of Co- and homopolymer macromolecules in the presence of an amphiphilic substrateстатья

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Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.

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[1] Ablyazov P. N., Vasilevskaya V. V., Khokhlov A. R. Destruction of globules of co- and homopolymer macromolecules in the presence of an amphiphilic substrate // Polymer Science - Series A. — 2009. — Vol. 51, no. 4. — P. 424–429. The destruction of a globule in the presence of a dimeric substrate composed of a hydrophilic group OP and a hydrophobic group H with a high affinity to hydrophobic H units of a macromolecule has been studied. Globules of the homopolymer H macromolecule and the macromolecule of the HP copolymer with proteinlike statistics of monomer unit distribution along a chain have been investigated. The destruction of a globule in such systems begins with the transformation of the globule's shape from spherical to disklike. At high substrate concentrations, the globule of the proteinlike copolymer is completely destroyed; under the same conditions, the homopolymer macromolecule forms a structure composed of two beads having a shape close to that of the oblate ellipsoid that are located symmetrically about a string connecting them. [ DOI ]

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