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Интеллектуальная Система Тематического Исследования НАукометрических данных |
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Fast protonic conductivity in crystalline benzenehexasulfonic acid hydratesстатья
- Авторы: Garanin Evgeny M., Tolmachev Yuriy V., Bunge Scott D., Khitrin Anatoly K., Turanov Alexander N., Malkovskiy Andrey, Sokolov Alexei P.
- Журнал: Journal of Solid State Electrochemistry
- Том: 15
- Год издания: 2010
- Издательство: Springer Verlag
- Местоположение издательства: Germany
- Первая страница: 549
- Последняя страница: 560
- DOI: 10.1007/s10008-010-1094-9
- Аннотация: We report on the crystal structures of two hydrates of benzenehexasulfonic acid, its water sorption isotherm, temperature- and humidity-dependent conductivity, along with 1H NMR studies. At comparable humidities and temperatures, this crystalline material shows conductivity similar to Nafion, which conducts protons via liquid water channels. We believe that the presented discovery of fast protonic conductivity in benzenehexasulfonic acid at low humidities is encouraging for further efforts in developing highly sulfonated polymers as membranes for fuel cells.
- Добавил в систему: Толмачёв Юрий Вячеславович