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Hybrid materials with antimicrobial properties based on hyperbranched polyaminopropylalkoxysiloxanes embedded with Ag nanoparticlesстатья
Статья опубликована в высокорейтинговом журнале
Статья опубликована в журнале из списка Web of Science и/или Scopus- Авторы: Vasil’kov Alexander, Migulin Dmitry, Naumkin Alexander, Volkov Ilya, Butenko Ivan, Golub Alexandre, Sadykova Vera, Muzafarov Aziz
- Журнал: Pharmaceutics
- Том: 15
- Год издания: 2023
- Издательство: MDPI
- Местоположение издательства: Basel, Switzerland
- Номер статьи: 809
- DOI: 10.3390/pharmaceutics15030809
- Аннотация: New hybrid materials based on Ag nanoparticles stabilized by a polyaminopropylalkoxysiloxane hyperbranched polymer matrix were prepared. The Ag nanoparticles were synthesized in 2-propanol by metal vapor synthesis (MVS) and incorporated into the polymer matrix using metal-containing organosol. MVS is based on the interaction of extremely reactive atomic metals formed by evaporation in high vacuum (10-4–10-5 Torr) with organic substances during their co-condensation on the cooled walls of a reaction vessel. Polyaminopropylsiloxanes with hyperbranched molecular architectures were obtained in the process of heterofunctional polycondensation of the corresponding AB2-type monosodiumoxoorganodialkoxysilanes derived from the commercially available aminopropyltrialkoxysilanes.The nanocomposites were characterized using transmission (TEM) and scanning (SEM) electron microscopy, X-ray photoelectron spectroscopy (XPS), powder X-ray diffraction (PXRD) and Fourier-transform infrared spectroscopy (FTIR). TEM images show that Ag nanoparticles stabilized in the polymer matrix have an average size of 5.9 nm. In the Ag-containing composite, the metal nanoparticles have a “core-shell” structure, in which the “core” and “shell” represent the M0 and Mδ+ states, respectively.Nanocomposites based on silver nanoparticles stabilized with amine-containing polyorganosiloxane polymers showed antimicrobial activity against Bacillus subtilis and Escherichia coli.
- Добавил в систему: Васильков Александр Юрьевич
Прикрепленные файлы
| № | Имя | Описание | Имя файла | Размер | Добавлен |
|---|---|---|---|---|---|
| 3. | Полный текст | Текст статьи | pharmaceutics-15-00809.pdf | 10,0 МБ | 18 июня 2024 [whitewolf2] |
| 4. | Экспертное заключение | Pharmaceutics.pdf | 405,5 КБ | 18 июня 2024 [VasilkovAYu] |