|
ИСТИНА |
Войти в систему Регистрация |
Интеллектуальная Система Тематического Исследования НАукометрических данных |
||
Overclocking Nitronyl Nitroxide Gold Derivatives in Cross-Coupling Reactionsстатья
- Авторы: Zayakin Igor, Tretyakov Evgeny, Akyeva Anna, Syroeshkin Mikhail, Burykina Julia, Dmitrenok Andrey, Korlyukov Alexander, Nasyrova Darina, Bagryanskaya Irina, Stass Dmitri, Ananikov Valentine
- Журнал: Chemistry - A European Journal
- Год издания: 2022
- Издательство: John Wiley & Sons Ltd.
- Местоположение издательства: United Kingdom
- DOI: 10.1002/chem.202203118
- Аннотация: Nitronyl nitroxides are functional building blocks in cutting-edge research fields, such as the design of molecular magnets, the development of redox and photoswitchable molecular systems and the creation of redox-active components for organic and hybrid batteries. The key importance of the nitronyl nitroxide function is to translate molecular-level-optimized structures into nano-scale devices and new technologies. In spite of great importance, efficient and versatile synthetic approaches to these compounds still represent a challenge. Particularly, methods for the direct introduction of a nitronyl nitroxide moiety into aromatic systems possess many limitations. Here, we report gold derivatives of nitronyl nitroxide that can enter Pd(0)-catalysed cross-coupling reactions with various aryl bromides, affording the corresponding functionalized nitronyl nitroxides. Based on the high thermal stability and enhanced reactivity in catalytic transformation, a new reagent is suggested for the synthesis of radical systems via a universal cross-coupling approach
- Добавил в систему: Корлюков Александр Александрович
Прикрепленные файлы
| № | Имя | Описание | Имя файла | Размер | Добавлен |
|---|---|---|---|---|---|
| 1. | Полный текст | CEJ2022-e202203118_.pdf | 2,0 МБ | 22 декабря 2022 [akorlyukov] |