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Decatungstate-Catalyzed Photochemical Synthesis of Enaminones from Vinyl Azides and Aldehydesстатья
Статья опубликована в высокорейтинговом журнале
Статья опубликована в журнале из списка Web of Science и/или Scopus- Авторы: Paveliev S.A., Segida O.O., Mulina O.M., Krylov I.B., Terent’Ev A.O.
- Журнал: Organic Letters
- Год издания: 2022
- Издательство: American Chemical Society
- Местоположение издательства: United States
- DOI: 10.1021/acs.orglett.2c03364
- Аннотация: Visible light-induced synthesis of enaminones from vinyl azides and aldehydes under decatungstate photocatalysis was developed. The reaction proceeds via acyl radical generation from aldehyde, followed by its addition to vinyl azide, nitrogen elimination, hydrogen atom abstraction by the intermediate iminyl radical, and tautomerization. Photochemical synthesis was efficiently conducted under both batch and flow conditions. The method can be applied to various vinyl azides and aldehydes and provides the desired products in 15-72% yields. © 2022 American Chemical Society.
- Добавил в систему: Малошицкая Ольга Александровна