Matrix Effects of Heterochain Polymers in Acceptor-Catalytic Copolyesterificationстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 18 марта 2017 г.
Местоположение издательства:Road Town, United Kingdom
Первая страница:40
Последняя страница:44
Аннотация:The acceptor–catalytic copolyesterification of terephthaloyl chloride with bisphenol and glycol in the presence of heterochain polymeric matrices, such as poly(phenylquinoxaline), poly(ethylene oxide), and poly(naphthoyleneimide benzimidazole), was studied. The discovered structural and kinetic matrix effects were shown to affect the microstructure of the produced copolymers and the reactivity of diols. Specifically, it was established that the effective activity of OH alcoholic groups increases under the action of polymeric matrices, while the effective activity of OH phenolic groups decreases; thus, the reactivities of hydroxyl-containing monomers level off.