Using Minisci Reaction for Modification of the tris-Dioximate Metal Clathrochelates: Free-Radical Substitution at the Glyoximate Fragment of an Iron(II)-Encapsulating Cage Frameworkстатья
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Дата последнего поиска статьи во внешних источниках: 20 мая 2017 г.
Аннотация:An iron(II) clathrochelate having methylglyoxime rib fragment was treated with Fe(II)/t-BuOOH in 1,4-dioxane. The
reaction resulted in substitution of the aldoxime hydrogen with 1,4-dioxanyl fragment by virtue of Minisci reaction
mechanism. The resultant cage complex was identified with single crystal XRD, mass-spectrometry, 1H, 13C, 19F, 11B NMR
spectroscopy, and examined with UV-Vis and IR spectroscopy. This reaction extends the range of synthetic approaches
applicable for the functionalization of tris-dioximate cage complexes.