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Reactions of beta-dioxo compounds with hydrogen peroxide at low temperaturesстатья
Информация о цитировании статьи получена из
Web of Science
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 28 мая 2015 г.
- Авторы: Serebrennikov L.V., Golovkin A.V., Davlyatshin D.I., Shevelkov V.F.
- Журнал: Russian Journal of Physical Chemistry A
- Том: 82
- Номер: 4
- Год издания: 2008
- Издательство: Pleiades Publishing, Ltd
- Местоположение издательства: Road Town, United Kingdom
- Первая страница: 558
- Последняя страница: 564
- DOI: 10.1134/S0036024408040092
- Аннотация: —The paper presents the results obtained for the malonic aldehyde–hydrogen peroxide and β-oxobutanal–hydrogen peroxide systems. The systems were studied by IR spectroscopy in xenon matrices. The potential energy surfaces and vibrational spectra of the molecules that could occur in these systems were calculated quantum-chemically. As distinct from similar systems with monoaldehydes and α-dioxo compounds, the first stage of the reactions that occurred in the systems under consideration involved the decomposition of hydrogen peroxide with the formation of atomic oxygen, whose secondary reactions determined the set of eaction products.
- Добавил в систему: Серебренников Леонид Владимирович