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Интеллектуальная Система Тематического Исследования НАукометрических данных |
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Synthesis and Reactivity in Ethylene Oligomerization by Heteroscorpionate Trichlorochromium (III) ComplexesТезисы2017тезисы доклада Тезисы
- Авторы: Konstantinov A.V., Zubkevich Sergey V., Kasim Magomedov, Gagieva Svetlana C., Tuskaev Vladislav A., Sabanov Vladimir K.
- Сборник: Марковниковские чтения: Органическая химия от Марковникова до наших дней
- Тезисы
- Год издания: 2017
- Аннотация: Herein we report synthesis of new chromium (+3) binuclear complex with biphenyl frame, that was obtained by reaction of deprotonated ligand with CrCl3(THF)3 according to Scheme 1. This ligand is scorpionate-like, but provides the ability to synthesize binuclear compounds with potential different properties. The resulting complex was characterized with IR, NMR and mass-spectroscopy and tested for its ability to polymerize/oligomerize ethylene upon activation with MAO and several other organoaluminium compounds. The catalyst showed moderate activity and produced mostly polyethylene.
- Добавил в систему: Гагиева Светлана Черменовна