|
ИСТИНА |
Войти в систему Регистрация |
Интеллектуальная Система Тематического Исследования НАукометрических данных |
||
Proton tunneling assisted by the intermolecular vibration excitation. Temperature dependence of the proton spin‐lattice relaxation time in benzoic acid powderстатья
Информация о цитировании статьи получена из
Scopus,
Web of Science
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 8 сентября 2021 г.
- Авторы: Sakun V.P., Vener M.V., Sokolov N.D.
- Журнал: Journal of Chemical Physics
- Том: 105
- Номер: 2
- Год издания: 1996
- Издательство: AIP Publishing
- Местоположение издательства: United States
- Первая страница: 379
- Последняя страница: 387
- DOI: 10.1063/1.471914
- Аннотация: Temperature dependence of the proton spin‐lattice relaxation time (T1) in powdered benzoic acid dimer and in its deuterated analog is calculated. The model assumes that two protons (deuterons) synchronously move in the double‐minimum potential of the dimer. The two‐dimensional potential energy surface was constructed previously, which adequately describes the static properties of the hydrogen‐bonded complex. The important characteristics of this potential are a very strong mode coupling and a very high proton potential barrier (≳25 kcal/mol), whereas the experimental activation energy for the proton transfer is known to be on the order of 1 kcal/mol only. This apparent discrepancy is removed by our suggestion that the proton transfer is driven by the transitions between OHO fragment vibrational levels under the action of random forces of the surrounding. The excitation of the low‐frequency intermolecular vibrations assists such transfer mechanism strongly. Using four fitting parameters to allow for the medium repolarization, the calculated T1 temperature dependence is found to be in good agreement with the experiments in the natural and deuterated benzoic acid dimer. The agreement is best at high temperature where the apparent activation energy for proton transfer was found to be 2.3 kcal/mol.
- Добавил в систему: Венер Михаил Владимирович