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Logical-Information Model of Energy-Saving Production of Organic Sulfur Compounds from Low-Molecular Sulfur Waste Fuel Oilстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 13 января 2021 г.
- Авторы: Meshalkin Valery, Shinkar Elena, Berberova Nadezhda, Pivovarova Nadezhda, Ismagilov Foat, Okhlobystin Andrey
- Журнал: Energies
- Том: 13
- Номер: 20
- Год издания: 2020
- Издательство: MDPI
- Местоположение издательства: Basel, Switzerland
- Первая страница: 5286
- DOI: 10.3390/en13205286
- Аннотация: A logical-informational model of energy resource-efficient chemical technology for the utilization of hydrogen sulfide and low molecular alkanethiols, which are toxic and difficult to remove sulfur components of residual fuel (fuel oil), is proposed. Based on the IDEF1 methodology and existing knowledge about the technological processes of the demercaptanization of various hydrocarbon raw materials (oils, gas condensates), a scheme for the production of organic sulfur compounds from sulfur waste extracted from fuel oil has been modeled. For a sufficiently complete removal of hydrogen sulfide and low molecular weight alkanethiols, energy- and resource-saving stages of the technological process have been developed, which are implemented by ultrasonic and/or magnetic treatment of fuel oil. It is proposed to use the combined action of two alternative methods of processing fuel oil to increase the efficiency of cleaning fuel oil from sulfur components. For the first time, an approach has been developed to utilize unwanted sulfuric impurities contained in fuel oil by involving electric and microwave synthesis in green technological processes, to obtain practically useful organic sulfur compounds with biological activity. It is shown that the use of one-electron oxidant thiols and hydrogen sulfide in organic media leads to the synthesis of organic disulfides and elemental sulfur. Indirect (with the use of mediators) electrosynthesis contributes to the cyclic conduct of the technological process, an increase in efficiency and a decrease in energy consumption compared to the direct (on electrodes) initiation of sulfur components.
- Добавил в систему: Мешалкин Валерий Павлович