Molecular recognition and catalysis: From macrocyclic receptors to molecularly imprinted metal complexesстатья
Информация о цитировании статьи получена из
Web of Science ,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
Авторы:
Karakhanov E.A. ,
Karapetyan L.M. ,
Kardasheva Y.S. ,
Maksimov A.L. ,
Runova E.A. ,
Skorkin V.A. ,
Terenina M.V.
Журнал:
Macromolecular Symposia
Том:
235
Год издания:
2006
Издательство:
John Wiley & Sons Ltd.
Местоположение издательства:
United Kingdom
Первая страница:
39
Последняя страница:
51
DOI:
10.1002/masy.200650306
Аннотация:
The results of studying a number of reactions catalyzed by several types of soluble macromolecular catalytic systems capable of selectively binding organic substrates, namely, modified cyclodextrins, calixarenes and dendrimers are presented. The use of modified cyclodextrins as components of a catalytic system in the phenol and benzene hydroxylation by hydrogen peroxide allows one both to increase the catalytic activity and to change significantly the chemical selectivity. Phosphorilated calixarene - Rh catalytic systems was found to be catalytically active in hydroformylation of linear alkenes C 7-C 12. The results of experiments on the oxidation of C 7-C 16 alkenes show that, when the ligand is the dendrimer molecule, the fraction of forming methyl ketones substantially increases for the substrates C 7-C 9. For the higher alkenes, this effect is not observed. © 2006 WILEY-VCH Verlag GmbH & Co. KGaA.
Добавил в систему:
Максимов Антон Львович