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KTiOPO4-structured electrode materials for metal-ion batteries: A reviewстатья
Статья опубликована в высокорейтинговом журнале
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 8 января 2021 г.
- Авторы: Fedotov Stanislav S., Samarin Aleksandr Sh, Antipov Evgeny V.
- Журнал: Journal of Power Sources
- Том: 480
- Год издания: 2020
- Издательство: Elsevier BV
- Местоположение издательства: Netherlands
- Номер статьи: 228840
- DOI: 10.1016/j.jpowsour.2020.228840
- Аннотация: The success story of the triphylite-type LiFePO4 immediately boosted the development of numerous classes of polyanion-based electrode materials for metal-ion batteries. A number of advantages including thermal and structural stability, polyanionic inductive effect, and variety of crystal types and chemical compositions render these materials attractive for grid and large-scale applications ensuring high safety standards, environmental friendliness and cost benefits. In this review, we focus on a specific family of polyanion-based electrode materials adopting the KTiOPO4-type structure that captured particular attention recently due to the unique 3D-framework. This framework features thermal, structural and long-term electrochemical cycling stability, fast ionic transport, possibility to accommodate two alkali ions per transition metal cation enabling multi-electron transitions, and unprecedented high electrode potentials for a specific redox couple among all known polyanion materials. The recent advances and overview of KTiOPO4-type and related positive and negative electrode materials for metal-ion batteries are presented with a special emphasis on the interrelations between crystal structure peculiarities and electrochemical properties.
- Добавил в систему: Федотов Станислав Сергеевич