A novel optical sensor for metal ions based on ground-state intermolecular charge-transfer complexationстатья
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Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
Аннотация:[GRAPHICS] A derivative of dipyridylethylene 2 was synthesized in order to study intermolecular coordination between the 18-crown-6 ether units of bis-crown stilbene 1 and the NH3+ groups of 2, In acetonitrile solution, the formation of a supramolecular complex is evidenced by a considerable upfield shift of the H-1 NMR signals from the aromatic and olefinic protons, Emission quenching and the appearance of a new absorption band in the visible spectral region indicate the formation of a charge-transfer complex. The addition of Ba2+ to a solution of the complex leads to significant fluorescence enhancement and to the disappearance of the charge-transfer absorption band.