Competition Between Saturated and Unsaturated Components for Reacting with Emerging 1:1 Adduct Radical... in Free-Radical Nonbranched-Chain Processes of Initiated Addition to Molecular Double Bonds in Binary Systemsстатья

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1. Полный текст The kinetics of free-radical nonbranched-chain processes of addition to unsaturated compounds (such as alkenes, formaldehyde, dioxygen) was investigated. The proposed schemes include the reaction competing with chain propagation reactions through a reactive free radical. The chain evolution stage in these schemes involves three or four types of free radicals. One of them – СН2=С(СН3)ĊН2, СН2=СНĊНОН, НĊ=O, o-СН3С6Н4СН2O4•, or HO4• – is relatively low-reactive and inhibits the chain process by shortening of the kinetic chain length. The energetics of the key radical-molecule reactions is considered. M.M._Silaev_IJSRCH_2020_51_6-36_website.pdf 917,4 КБ 19 марта 2020 [SilaevMM]