Self-Assembly of Rod-Like Copolymers into Monolayers: A Simple Theoretical Estimate of Molecular Recognition Qualityстатья

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Дата последнего поиска статьи во внешних источниках: 26 сентября 2016 г.

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[1] Berezkin A. V., Lazutin A. A. Self-assembly of rod-like copolymers into monolayers: A simple theoretical estimate of molecular recognition quality // Macromolecular Theory and Simulations. — 2008. — Vol. 17, no. 7-8. — P. 410–420. A discrete model of a monolayer, consisting of identical rod-like copolymer molecules, is suggested. The influence of the copolymer's composition and sequence on its self-assembly was studied. Thermodynamic quantities of monolayers were calculated. It is shown that the system undergoes an order-disorder transition upon temperature increase. The most regular monolayers are formed by copolymers with quasi-random sequences. Nevertheless, the monomer composition of such good sequences can vary over a wide range. It is shown that homopolymers, copolymers with a predominance of one-type monomer units and copolymers consisting of a small number of large blocks have a reduced ability to self-assembly. [ DOI ]

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