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Synthesis and study of C-substituted methylthio derivatives of cobalt bis(dicarbollide)статья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 28 февраля 2020 г.
- Авторы: Stogniy Marina Yu, Kazheva Olga N., Chudak Denis M., Shilov Gennady V., Filippov Oleg A., Sivaev Igor B., Kravchenko Andrey V., Starodub Vladimir A., Buravov Lev I., Bregadze Vladimir I., Dyachenko Oleg A.
- Журнал: RSC advances
- Том: 10
- Номер: 5
- Год издания: 2020
- Издательство: Royal Society of Chemistry
- Местоположение издательства: United Kingdom
- Первая страница: 2887
- Последняя страница: 2896
- DOI: 10.1039/c9ra08551c
- Аннотация: The C-methylthio derivatives of cobalt bis(dicarbollide) were synthesized by reaction of anhydrous CoCl2 with nido-carborane 17-MeS-7.8-C2B9 H11]- and isolated as a mixture of rac-ll.1'-(MeSb-3.3'-Co(l.2-C2B9H10bl- and meso-ll.2'-(MeSb-3.3'-Co(l.2-C2B9H10'2t isomers. The structures of both isomers were studied using DFT quantum chemical calculations. The most preferable geometry of rotamers and the stabilization energy of C-methylthio derivatives of cobalt bis(dicarbolide) were calculated. The (BEDT-TTFlll.1' -(MeSb-3.3'-Co(l.2-C2B9H10)2] salt was prepared and its structure was determined by single crystal X-ray diffraction. The cisoid conformation of the rac-11.1' -(MeSb-3.3'-Co(l.2-C2B9H10blanion is stabilized by short intramolecular CH···S hydrogen and BH···S chalcogen bonds between the dicarbollide ligands,, that is in good agreement with the data of quantum chemical calculations.
- Добавил в систему: Стогний Марина Юрьевна
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