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Overlimiting current due to electro-diffusive amplification of the second Wien effect at a cation-anion bipolar membrane junctionстатья Исследовательская статья
Статья опубликована в высокорейтинговом журнале
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 24 января 2020 г.
- Авторы: Jarrod Schiffbauer, Ganchenko Nataly Yu, Ganchenko Georgy S., Demekhin Evgeny A.
- Журнал: Biomicrofluidics
- Том: 12
- Год издания: 2018
- Издательство: AIP Publishing
- Местоположение издательства: United States
- Первая страница: 064107
- DOI: 10.1063/1.5066195
- Аннотация: Numerical simulations are presented for the transient and steady-state response of a model electrodiffusive cell with a bipolar ion-selective membrane under electric current. The model uses a continuum Poisson-Nernst-Planck theory including source terms to account for the catalytic second Wien effect between ionogenic groups in the membranes and resolves the Debye layers at interfaces. The resulting electric field at the membrane junction is increased by as much as four orders of magnitude in comparison to the field external to the membrane. This leads to a significant amplification of the second Wien effect, creating an increased ionic flux due to the catalytic decomposition of water. The effect also induces an exaltation effect wherein the salt ion flux undergoes a concomitant increase as well. The interplay of effects results in a unique over-limiting current mechanism due to concentration polarization internal, rather than external, to the membranes. In addition to the case of two equal but oppositely charged membranes under the standard simplifying assumption of equal ionic diffusivities, two variations on this model are studied. Asymmetric diffu- sivities, representative of the actual mobility difference in dissociated water ions, and the effect of the membrane charge density ratio were also considered. The latter elu- cidates an overlimiting current shift mechanism for DNA adsorption on anion-selec- tive membranes proposed by Slouka et al. [Langmuir 29, 8275 (2013)]. The former provides more realistic picture of multi-ion transport and demonstrates a surprising steady-state effect due to the asymmetry in the diffusivity of hydroxide and hydronium.
- Добавил в систему: Ганченко Наталья Юрьевна