INFLUENCE OF METALS CHLORIDES ON OIL-SLIME THERMOCATALYTIC PROCESSINGстатья
Статья опубликована в высокорейтинговом журнале
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Дата последнего поиска статьи во внешних источниках: 13 ноября 2019 г.
Аннотация:The goal of this research is the development of the method of oil-slime recycling. In the present paper we report on the results of the process of oil-containing waste catalytic pyrolysis with such metals chlorides as k{cyrillic}Cl, NaCl, ZnCl2, MgCl2·6n{cyrillic}2O{cyrillic}, AlCl3·6n{cyrillic}2O{cyrillic}, FeCl2·4n{cyrillic}2O{cyrillic}, FeCl3·6n{cyrillic}2O{cyrillic}, CoCl2·6n{cyrillic}2O{cyrillic} and NiCl2·6n{cyrillic}2O{cyrillic}. The highest conversion of oil-slime into gaseous and liquid products was observed in the presence of iron subgroup metals chlorides. The maximum conversion was obtained in the presence of CoCl2. The increase of the conversion into gaseous and liquid products in the presence of CoCl2 was 41.2wt.% and 8.5wt.%, respectively, compared to a non-catalytic process. The optimal conditions of the oil-slime pyrolysis process are 500°C and cobalt chloride content of 5wt.%.