One‐Pot Catalytic Synthesis of Aniline‐Copolymer‐Containing Reactive Aldehyde Groups Using a Laccase‐Mediator Systemстатья
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Дата последнего поиска статьи во внешних источниках: 11 ноября 2019 г.
Аннотация:Laccase‐mediator systems (LMS) are extensively used both for degradation of various xenobiotics and synthesis of new compounds. In this work a laccase‐mediator system was applied to copolymerization of aniline and 2‐aminophenythyl alcohol on a ‘soft’ poly(2‐acrylamido‐2‐methyl‐1‐propansulfonic acid) (PAMPS) template. The one‐pot biocatalytic reaction resulted in obtaining a conducting copolymer/PAMPS complex with reactive aldehyde groups which enabled grafting the physiologically active compound 3,4‐dihydroxy‐L‐phenylalanine (DOPA) to it.