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The H2-D2 exchange reaction catalyzed by gold nanoparticles supported on $\upgamma$-Al2O3: Effect of particle size on the reaction rateстатья
Информация о цитировании статьи получена из
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Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 11 ноября 2019 г.
- Авторы: Abkhalimov Evgeny V., Boeva Olga A., Odintzov Alexandr A., Solovov Roman D., Zhavoronkova Ksenia N., Ershov Boris G.
- Журнал: Catalysis Communications
- Том: 133
- Год издания: 2020
- Издательство: Elsevier BV
- Местоположение издательства: Netherlands
- Первая страница: 105840
- DOI: 10.1016/j.catcom.2019.105840
- Аннотация: Gold nanoparticles supported on γ-Al2O3 catalyzed the hydrogen isotope exchange Н2+D2 at low temperatures, ca. 77 K. The specific catalytic activity increases by a factor of ~800 as the particle size decreases from 39.3 to 0.7 nm. A correlation has been established between the catalytic activity of nanoparticles of different size and the concentration of low-coordination gold surface atoms. Apparently, the obtained empirical equations can be used to estimate the specific catalytic activity of gold nanoparticles of various sizes.
- Добавил в систему: Абхалимов Евгений Владиленович
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| [1] | The h2-d2 exchange reaction catalyzed by gold nanoparticles supported on -al2o3: Effect of particle size on the reaction rate / E. V. Abkhalimov, O. A. Boeva, A. A. Odintzov et al. // Catalysis Communications. — 2020. — Vol. 133. — P. 105840. Gold nanoparticles supported on γ-Al2O3 catalyzed the hydrogen isotope exchange Н2+D2 at low temperatures, ca. 77 K. The specific catalytic activity increases by a factor of ∼800 as the particle size decreases from 39.3 to 0.7 nm. A correlation has been established between the catalytic activity of nanoparticles of different size and the concentration of low-coordination gold surface atoms. Apparently, the obtained empirical equations can be used to estimate the specific catalytic activity of gold nanoparticles of various sizes. [ DOI ] |