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Testing of the ways for synthesis of new nonlinear optical epoxy-based polymers with azochromophores in the side chainстатья
Статья опубликована в высокорейтинговом журнале
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 11 ноября 2019 г.
- Авторы: Nazmieva G.N., Vakhonina T.A., Ivanova N.V., Mukhtarov A.Sh, Smirnov N.N., Yakimansky A.V., Balakina M.Yu, Sinyashin O.G.
- Журнал: European Polymer Journal
- Том: 63
- Год издания: 2015
- Издательство: Pergamon Press Ltd.
- Местоположение издательства: United Kingdom
- Первая страница: 207
- Последняя страница: 216
- DOI: 10.1016/j.eurpolymj.2014.12.003
- Аннотация: New polymer materials with quadratic nonlinear optical (NLO) response were synthesized on the basis of bisphenol A diglycidyl ether and p-aminobenzoic acid oligomers with azochromophores in side chains. The reactive polyether polyols were obtained either in solution, or in the bulk, the latter approach being found to be preferable as it provides obtaining oligomers with rather high molecular weight and high yield. The incorporation of chromophores into the oligomers side chain was carried out by etherification reaction using two synthetic approaches: in two steps, when an aniline-containing oligomer precursor is first obtained and then used in an azo-coupling reaction, giving the desired azochromophore-containing oligomer, or in one step via a direct attachment of a hydroxyl-containing azochromophore to the reactive oligomer. The advantage of the one-stage procedure is established, since the oligomer functionalization degree with chromophore groups reached 70 mol% in this case. The synthesized oligomers are characterized by high thermal stability and heat resistance; they demonstrate good film-forming ability. NLO coefficients, d(33), of corona-poled films of the materials based on linear oligomers and cross-linked polymers amount to similar to 22 and 35.2 pm/V, respectively. The cross-linked materials are shown to have moderate temporal stability of the second-order nonlinear optical characteristics. (C) 2014 Elsevier Ltd. All rights reserved.
- Добавил в систему: Якиманский Александр Вадимович