Configurationally stable asymmetric nitrogen atom in the palladium(II) aminophosphine complexстатья
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Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
Аннотация: The synthesis of a new optically active aminophosphine ligand i-Pramphos, containing a
potentially stereogenic nitrogen atom, from (S)-N-isopropyl-N-methyl-alpha-methylbenzylamine
is described; its complex with palladium(II) chloride was obtained. NMR spectroscopy
revealed that the coordination of the aminophosphine with the metal resulted in stereospecific
locking of the donor nitrogen atom in only one of two possible configurations.