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The kinetics of α-hydroxyalkyl radical addition to 2-propene-1-ol and formaldehydeстатья
Информация о цитировании статьи получена из
Web of Science
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 20 января 2016 г.
- Авторы: Silaev M.M., Bugaenko L.T.
- Журнал: Kinetics and Catalysis
- Том: 35
- Номер: 4
- Год издания: 1994
- Издательство: Maik Nauka/Interperiodica Publishing
- Местоположение издательства: Russian Federation
- Первая страница: 463
- Последняя страница: 467
- Аннотация: A kinetic model has been developed for competitive short-chain free-radical processes characterized by an extreme dependence of the rate on the concentration of an unsaturated compound in binary systems consisting of saturated (in excess) and unsaturated components. The model makes it possible to describe the entire experimental curve with a maximum by a single kinetic equation with two or three parameters subject to direct determination. Mathematical modeling of the processes of formation of 1.4- and 1.2-diols during γ-radiolysis of systems saturated alcohol–2-propen-1-ol or formaldehyde was carried out. The calculated kinetic curves agree well with the experimental dependencies. A quantitative assessment of the kinetic parameters of the processes, including the rate constants of addition reactions of α-hydroxyalkyl radicals from saturated alcohols to a carbon atom at the double bond of the molecule of the unsaturated component, is given.
- Добавил в систему: Силаев Михаил Михайлович
Прикрепленные файлы
| № | Имя | Описание | Имя файла | Размер | Добавлен |
|---|---|---|---|---|---|
| 1. | Полный текст | A kinetic model has been developed for competitive short-chain free-radical processes characterized by an extreme dependence of the rate on the concentration of an unsaturated compound in binary systems consisting of saturated (in excess) and unsaturated components. The model makes it possible to describe the entire experimental curve with a maximum by a single kinetic equation with two or three parameters subject to direct determination. | M.M._Silaev_Kinetics_and_Catalysis_1994_354_463-467.pdf | 4,0 МБ | 25 мая 2023 [SilaevMM] |