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Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
Аннотация:The reaction between Pd(3)(OOCMe)(6) and Ag(2)(OOCMe)(2) afforded the first palladium-silver heterometallic acetate-bridged complex Pd(II)[(mu-OOCMe)(2)Ag(I)(HOOCMe)(2)](2) (1). The molecular geometry and electronic structure of 1 were studied by single-crystal XRD and quantum-chemical DFT calculations. Thermal transformations of 1 in vacuo and under Ar, H(2) produced PdAg alloy nanoparticles characterized with powder XRD and EXAFS. (C) 2011 Elsevier B. V. All rights reserved.