CAGE EFFECT IN THE SOLID-PHASE - CALCULATION OF QUANTUM YIELDS OF STABILIZED RADICALS ON THE BASIS OF A FREE-VOLUME MODELстатья
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Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
Аннотация:A method of evaluating the quantum yield of stabilized radicals in solid phase molecular homolytic photodecomposition is suggested. The calculation is based on a free volume model. It is assumed that the radical escape from the matrix cage occurs only where a free volume larger than the volume of the fragment coming out of the cage is concentrated near the decomposed molecule. The available experimental data on the quantum yields of the stabilized radicals are in good agreement with the calculated ones.