TEMPERATURE EFFECTS IN 2-DIMENSIONAL CONDENSATION OF ORGANIC-COMPOUNDS ON ELECTRODESстатья
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Дата последнего поиска статьи во внешних источниках: 27 мая 2015 г.
Аннотация:Results of investigations of two-dimensional condensation of surface-active organic compounds in various supporting electrolytes obtained by the authors in this work and earlier are analyzed. Calculations based on the Ising model show the growth in surface activity of electrolyte to strengthen the adsorption layer and its thermal stability. A similar effect is achieved by substituting the keto-group for the hydroxy-group in the organic molecule. Calculations using the Frumkin adsorption model lead to a tentative conclusion that, when analyzing temperature shifts of adsorption-desorption potentials for condensed layers of surface-active organic compounds in concentrated supporting electrolytes, one should take into account temperature dependence of the salting-out coefficient.