Spatial-dispersion of electron-transfer probabilityстатья
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Дата последнего поиска статьи во внешних источниках: 18 марта 2016 г.
Аннотация:Recombination and ionization rate constants were calculated taking into account the spatial dispersion of reaction free and reorganization energies. The conditions were found under which the reactions are contact and the contact estimation of their rate is invalid. The spatial dispersion of transfer probability was shown to be responsible for the smoothing of the multichannel structure of the free energy "gap" dependence of the rate constant.