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Effects of two-dimensional condensed layers of organic substances on electrochemical reaction kineticsстатья
Информация о цитировании статьи получена из
Scopus,
Web of Science
Дата последнего поиска статьи во внешних источниках: 12 октября 2013 г.
- Авторы: Fedorovich N.V., Stenina E.V., Damaskin B.B., Girlya L.N.
- Журнал: SOVIET ELECTROCHEMISTRY
- Том: 21
- Номер: 7
- Год издания: 1985
- Первая страница: 939
- Последняя страница: 944
- Аннотация: If the concepts developed by the authors are correct and a species undergoes discharge which is on top of the two-dimensional condensed layer of organic material, then under these conditions one should not find reduction of anions of the second group, where the elementary discharge act consists in the simultaneous transfer of an electron and a proton to the anion undergoing discharge, the proton coming from a proton donor which is electrostatically or specifically adsorbed in the electrode surface. It is also shown that the reaction zone for anion discharge is located at the adsorbed layer/solution interface when a condensed OSA layer is present on the electrode; therefore, the proton donors present at this interface are not directly adsorbed on the electrode, and moreover, the field strength in the reaction zone in this case is much lower than in the absence of OSA layers, both because of the decrease in electrode charge and because of the larger distance of the reaction zone from the surface.
- Добавил в систему: Дамаскин Борис Борисович