|
ИСТИНА |
Войти в систему Регистрация |
Интеллектуальная Система Тематического Исследования НАукометрических данных |
||
Phase transitions, structure and ion conductivity of zirconium hydrogen phosphates, H1 +/- XZr2-XMX(PO4)(3)center dot H2O (M = Nb, Y)статья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
- Авторы: Stenina I.A., Zhizhin M.G., Lazoryak B.I., Yaroslavtsev A.B.
- Журнал: Materials Research Bulletin
- Том: 44
- Номер: 7
- Год издания: 2009
- Издательство: Pergamon Press Ltd.
- Местоположение издательства: United Kingdom
- Первая страница: 1608
- Последняя страница: 1612
- DOI: 10.1016/j.materresbull.2009.01.011
- Аннотация: Structure transformations and proton conductivity of hydrogen zirconium phosphates with the NASICON structure, H1 +/- XZr2-XMX(PO4)(3)center dot H2O (X = 0, 0.02, and 0.1, M = Nb, Y), were studied by X-ray powder diffraction, calorimetry, IR- and impedance spectroscopy. Substitution of zirconium by niobium leads to decrease of the lattice parameters, while yttrium doping leads to their increase. H0.9Zr1.9Nb0.1(PO4)(3) structure was determined at 493 and 733 K. This phase crystallizes in rhombohedral space group R (3) over barc with lattice parameters a = 8.8564(5) angstrom, c = 22.700(1) angstrom at 493 K and a = 8.8470(2) angstrom, c = 22.7141(9) angstrom at 733 K. The a parameter and lattice volume were found to decrease with temperature increasing. Structure transformations upon heating are caused mainly by the decrease of the M1 site and C cavities. Ion conductivity of obtained materials was found to increase in humid atmosphere. Activation energies of conductivity were calculated. Rhombohedral-triclinic phase transition found by X-ray powder diffraction was proved by calorimetry data. According to XRD and IR spectroscopy data hydrogen bond in HZr2(PO4)(3) was found to be weaker than in hydrated material. (C) 2009 Elsevier Ltd. All rights reserved.
- Добавил в систему: Лазоряк Богдан Иосипович